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Conversion process of hydrocarbon oils

Patent Number: US6156190
Date of Patent: 2000-12-05
Inventor(s): Xia Guofu(CN); Zhu Mei(CN); Min Enze(CN); Shi Yahua(CN); Tao Zhiping(CN); Pang Guici(CN); Li Mingfeng(CN); Ran Guopeng(CN); Huang Haitao(CN); Zhang Runqiang(CN); Li Jian(CN); Nie Hong(CN)
Applicant(s): CHINA PETROCHEMICAL CORP (CN);RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC(CN)
Application Number: 272246 19990319
Priority Number(s): CN98100760 19980320
IPC Classification: C10G45/08 ; C10G69/04 ; B01J23/85
EC Classification: C10G69/06, B01J23/85, C10G45/08, C10G69/04
U.S. Classification: 208/216R;208/217;208/263;208/264
Equivalents: JP11323354, NO991360, IR26147, EP99105010.5-2104(IT, FR, DE, ES)


Abstract
A conversion process of hydrocarbon oils comprises at least a hydrodemercaptanization process, wherein said hydrodemercaptanization process comprises contacting a feedstock with a hydrofining catalyst containing a tungsten oxide and/or a molybdenum oxide, a nickel oxide and a cobalt oxide supported on an alumina under the conditions of hydrodemercaptanization, in which the content of said tungsten oxide and /or molybdenum oxide is from 4 wt % to less than 10 wt %, the nickel oxide content is 1 - 5wt %, the cobalt oxide content is 0.01- 1wt % based on the catalyst, and the ratio of total atom number of nickel and cobalt to total atom number of nickel, cobalt, tungsten and/or molybdenum is 0.3 - 0.9. Said process can be carried out at a lower temperature and a lower H/oil volume ratio.

 

 

Research Institute of Petroleum Processing, SINOPEC
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